
audiobook
by C. F. H. (Charles Francis Hitchcock) Allen
BOSTON UNIVERSITY GRADUATE SCHOOL THESIS META TOLUENE SULPHONIC ACID and RELATED COMPOUNDS Submitted by Charles Francis Hitchcock Allen (A.B., Boston University, 1919) In partial fulfilment of requirements for the degree of Master of Arts 1920
SULPHONATION OF ORTHO TOLUIDINE
SULPHONATION OF PARA TOLUIDINE
DIAZOTIZATION OF ORTHO TOLUIDINE SULPHONIC ACID.
PHYSICAL PROPERTIES OF THE DIAZO COMPOUND
DECOMPOSITION OF THE DIAZO COMPOUND
A STUDY OF THE SOLUTION OBTAINED BY THE DECOMPOSITION OF THE DIAZO COMPOUND
CONCLUSION
The thesis opens with a concise overview of how chemists of the 19th‑century wrestled with the sulfonation of toluene, tracing a line from Jaworsky’s first observations through a series of competing claims about whether the meta‑sulfonic acid ever formed. It reads like a scholarly detective story, recounting experiments with brominated toluene, potassium salts, and phosphorus pentachloride, while carefully noting where earlier researchers succeeded or fell short.
In the body of the work the author methodically reproduces and refines those classic reactions, preparing a series of salts, chlorides and amides and recording their melting points and solubilities with exacting precision. The discussion balances detailed laboratory procedure with thoughtful interpretation of what each result implies for the structure of the three possible isomers. Listeners who enjoy following the evolution of scientific ideas will find this historical chemistry investigation both informative and a vivid snapshot of early 20th‑century research practice.
Language
en
Duration
~39 minutes (37K characters)
Publisher of text edition
Project Gutenberg
Credits
Produced by Wayne Hammond and The Online Distributed Proofreading Team at http://www.pgdp.net (This file was produced from images generously made available by The Internet Archive)
Release date
2018-05-05
Rights
Public domain in the USA.
1895–1979
A meticulous organic chemist whose books helped map the chemistry of nitrogen-containing ring systems, he also played an important behind-the-scenes role in the early years of Organic Syntheses.
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